But Kylie, younger sister of the Kardashian girls, appeared distracted by her phone as she walked out ahead of him.
Date night? Cody Simpson and Kylie Jenner were pictured leaving a cinema in Los Angeles last night
Despite being spotted out on several dates, Simpson told Mail Online this week that he and Kylie are not a couple.
'Kylie and I laugh about the dating rumours,' he said on the red carpet of the Nick Awards. 'They (Kylie and sister Kendall) are very close friends of mine.'
Distracted: Despite Cody chivalrously holding the door open for Kylie, she seemed more interested in her phone
Kylie was casual in leggings, boots and a jumper, while Cody put a little more effort in, in jeans and a smart shirt.
Even though they protest romance rumours, seeing Cody was Kylie's first priority after flying home from the Dominican Republic just hours earlier.
Heartbreaker: The Australian singer is fast-becoming the next Justin Bieber
But the So Listen singer has revealed he has a crush on a fellow Aussie: Victoria's Secret model Miranda Kerr, who he nominated as his dream date.
Cody, who hails from Queensland, Australia, moved to Los Angeles last year to further his career after gaining an enormous YouTube following.